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Detailed Programme



MONDAY, AUGUST

8
9:00 – 10:15
Opening ceremony
10:15 – 10:45
Coffee break

Chair: V.P. Kukhar
plenary lectures
10:45
PL1
Direct Cupration of Fluoroform: From waste to high-value trifluoromethylated compounds
Vladimir V. Grushin
K&G Technologies LLC, WY, USA

11:30
PL2
Fluorine in peptide and protein engineering
B. Koksch
Freie Universität Berlin, Institute of Chemistry and Biochemistry, Takustr. 3,14195 Berlin, Germany email: beate.koksch@fu-berlin.de

12:15
PL3
Fluorination with an enzyme and applications towards positron emission tomography for clinical imaging
David O’Hagan
University of St Andrews, School of Chemistry, St Andrews, Fife, UK, KY16 9ST

13:00 - 14:30
Lunch

STREAM A
Chair: E. Magnier
14:30
A1.1-IL
Methods for the synthesis of CF3- and SF5-containing molecules using a building-block approach
Jean-Francois Paquin
Département de chimie
FQRNT Centre for Green Chemistry and Catalysis
FQRNT Network for Research on Protein Function, Structure, and Engineering
Université Laval, Québec, QC, CANADA G1V 0A6

15:00
A1.2-IL
Selective Synthesis of gem-Difluoromethylene Compounds
Hideki Amii
Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu, Japan

15:30
A1.3
“Omitted” examples of alkyl 2-bromo-2,2-difluoroacetate addition. Application for the synthesis of fluorinated amino acids
Ivan S. Kondratov, Maksym Ya. Bugera, Nataliya A. Tolmachova, Ganna G. Posternak, Gunter Haufe
Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, Murmanska Str. 1, Kyiv, 02660, Ukraine
Enamine Ltd, Chervonotkatska Str. 78, Kyiv, 02094, Ukraine

15:50 - 16:20
Coffee break

Chair: N. Shibata
16:20
A1.4-IL
Sulfur-containing reagents for fluorinated heterocycles synthesis
Yuriy G.Shermolovich
Institute of Organic Chemistry of National Academy of Sciences of Ukraine, Kiev, Ukraine

16:50
A1.5
Organocatalytic decarboxylative fluorination of highly substituted carboxylic acids
Kazutaka Shibatomi, Kazumasa Kitahara, Nozomi Sasaki, Misaki Katada, Zhihong Bao, Seiji Iwasa
Toyohashi University of Technology, Toyohashi. Japan

17:10
A1.6
Fluorine-containing reagents in parallel synthesis of small molecules for biological applications
Andrey Bogolubsky, Yurii Moroz, Pavel Mykhailiuk, Sergey Pipko, Anton Zhemera, Alexander Chuprina, Dmytro Mykytenko and Andrey Tolmachev
ChemBioCenter, Kyiv National Taras Shevchenko University, Kyiv, Ukraine

STREAM B
Chair: M. Lozinšek
14:30
B1.1-IL
An exciting study of homogeneous catalysis
Herbert W. Roesky, Z. Yang, P. P. Samuel, D. Koley, P. Parameswaran
Institute of Inorganic Chemistry University of Göttingen, Tammannstr. 4,37077 Göttingen, Germany

15:00
B1.2-IL
Recent progress in imidotungsten(VI) fluoride chemistry
Michael Gerken, Doug Turnbull, Stacey D. Wetmore
Department of Chemistry and Biochemistry and the Canadian Centre for Research in Advanced Fluorine Technologies, University of Lethbridge, Lethbridge, Alberta, Canada

15:30
B1.3
Spectroscopic Analysis Of Molten Flibe (2LiF-BeF2) For Application To Fluoride Salt Cooled High Temperature Nuclear Reactor (FHR)
Ruchi Gakhar and Raluca Scarlat
Heat and Mass Transport Group, Department of Engineering Physics,University of Wisconsin, Madison WI 53706

15:50 - 16:20
Coffee break

Chair: V. Timoshenko
16:20
B1.4-IL
Fluoro- And Hydridocyanoborate Anions
Johannes Landmann, Jan A. P. Sprenger, Christoph Kerpen, Lisa A. Bischoff, Michael Drisch, Katharina Duda, Eduard Bernhardt, Helge Willner, Nikolai Ignat’ev, Maik Finze
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

16:50
B1.5
Perfluoroalkyl Siloxan Derivatives
B. Hoge and N. Schwarze
Bielefeld University, Center for Molecular Materials Universitaetsstr. 25, 3615 Bielefeld, Germany

17:10
B1.6
(C2F5)3PF2 chemistry: it’s all about conditions, conditions, conditions
Julia Bader, Berthold Hoge, Nikolai Ignat’ev
Bielefeld University, Center for Molecular Materials, Universitaetsstr. 25, 33615 Bielefeld, Germany

TUESDAY, AUGUST

9

STREAM A
Chair: I.V. Komarov
9:00
A2.1-IL
Fluoroalkyl Amino Reagents (FAR) as Powerful Tool in Organic Synthesis
F. R. Leroux
University of Strasbourg, UMR CNRS 7509, COHA-lab, 25 Rue Becquerel, 67087 Strasbourg, France Joint CNRS-Bayer laboratory LCR C2OF

9:30
A2.2-IL
New applications of α, α -Difluoroalkylamino reagents in the synthesis of Fluoro containing Agrochemicals
S. Pazenok
Bayer AG, Alfred-Nobel-Straße 50, 40789 Monheim, Germany

10:00
A2.3
A general and efficient Pd-catalyzed rapid fluoroalkoxy¬lation of activated aryl bromides and bromo-chalcones
Raj Pal Singh, and T. M. Rangarajan
Fluoroorganic Laboratory, Center for Fire, Explosive and Environment Safety, Delhi, India

10:20
A2.4
Organocatalytic C-F bond activation with alanes
Alma D. Jaeger, Dieter Lentz
Institut für Chemie und Biochemie, Freie Universität Berlin, Germany

10:40 - 11:10
Coffee break

Chair: G. Haufe
11:10
A2.5-IL
Incorporation of CF3 and SCF3 group containing amino acids into peptides and hydrophobicity quantification
Thierry Brigaud
Laboratoire de Chimie Biologique (EA 4505), Université de Cergy Pontoise, 5 mail Gay Lussac, 95000 Cergy-Pontoise

11:40
A2.6-IL
Fluorinated amino acids, amines and diazo alkanes: Synthesis and application
Pavel K. Mykhailiuk
Enamine Ltd., Kyiv, Ukraine

12:10
А2.7
Synthesis of Hydrofluoroolefins and Olefinic Hydrofluoroethers
S. Peng, M. Nappa, V.A. Petrov, A.A. Filatov, Yu.L. Yagupolskii, N.V. Pavlenko, S.V. Shelyazhenko, M.M. Kremlev, A.I. Mushta, I.I. Gerus
The Chemours Company, Experimental Station, USA

12:30 - 14:00
Lunch

Chair: Y.L. Yagupolskii
14:00
A2.8-IL
Enantioselective trichloromethylation of MBH-fluorides with chloroform based on silicon-assisted C-F activation
Norio Shibata
Department of Nanopharmaceutical Sciences, Nagoya Institute of Technology Gokiso, Showa-ku, Nagoya, 466-8555, Japan

14:30
A2.9-IL
Fluorous ruthenium complexes for alkene metathesis. Synthesis, catalytical activity, stability, stereoselectivity and recycling
J. Kvíčala, J. Hošek, O. Šimůnek, V. Kolaříková, M. Babuněk, P. Lipovská, K. Kučnirová, M. Rybáčková
Department of Organic Chemistry, University of Chemistry and Technology, Prague, Technická 5, 166 28 Prague 6, Czech Republic

15:00
A2.10
N-Alkenyl and alkynyl S-perfluoroalkylated sulfoximines by copper coupling catalysis
Elsa Anselmi, Thanh Nghi Le, Sébastien Bouvet, Bruce Pegot, Patrick Diter, Emmanuel Magnier
Institut Lavoisier de Versailles, Université de Versailles-St-Quentin,Versailles cedex, France Infectiologie et Santé Publique, Université de Tours, Tours, France

15:20 - 15:50
Coffee break

Chair: Y.G. Shermolovich
15:50
A2.12-IL
Fluoroalkanesulfenamides: Versatile Reagents in Fluorine Chemistry
Thierry Billard
Institute of Chemistry and Biochemistry (ICBMS - UMR CNRS 5246), University of Lyon (France) CERMEP-in vivo imaging, Neurological hospital, Lyon (France)

16:20
A2.13
Strong Influence of the CF3 Group on the Course of the [3+2]-Cycloaddition of Thiocarbonyl S-Methanides with Fluorinated Enones
Grzegorz Mlostoń, Paulina Grzelak, Agnieszka Czyżewska
University of Łódź, Faculty of Chemistry, Department of Organic and Applied Chemistry, Tamka 12, PL-91-403 Łódź, Poland

16:40
A2.11
Recent developments in the preparation of monofluoroalkenes from 3-fluoro-3-halopropenes
J.-D. Hamel, M. Cloutier, M. Drouin, J.-F. Paquin
Université Laval, Quebéc, Canada

17:00 - 20:00
Poster Session with food & drinks

STREAM B
Chair: H.W. Roesky
9:00
B2.1-IL
New insights into the chemistry of molecular Fluorinated species under Cryogenic conditions
Sebastian Riedel, Helmut Beckers, Tony Stücker, Frenio Redeker, Felix Brosi
Institut für Chemie und Biochemie, FU Berlin, Berlin, Germany

9:30
B2.2-IL
New developments in xenon(II) and xenon(VI) oxide chemistry
James T. Goettel, Maria V. Ivanova, John D. DeBackere, Mark R. Bortulos, Héléne P.A. Mercier, and Gary J. Schrobilgen
Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada

10:00
B2.3
Complexes and co-crystals of krypton difluoride
Matic Lozinšek and Gary J. Schrobilgen
Department of Chemistry, McMaster University, Hamilton, Canada

10:20
B2.4
Crystal structures of the XeF6•nMF4 (M = Mn, Ti, Sn); more than just simple formulas
Zoran Mazej, Evgeny Goreshnik
Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Ljubljana Slovenia

10:40 - 11:10
Coffee break

Chair: M. Gerken
11:10
B2.5-IL
Synergistic activation of Fluorinated molecules at metal and silicon centersbr
Thomas Braun, Mike Ahrens, Theresia Ahrens, Erhard Kemnitz, Gisa Meißner, Anna Lena Raza, Falk Wehmeier, Lada Zámostná
Humboldt-Universität zu Berlin, Department of Chemistry, Brook-Taylor-Str. 2, 12489 Berlin, Germany

11:40
B2.6-IL
New components for lithium battery electrolytes
Gerd-Volker Röschenthaler, Tobias Böttcher, Nataliya Kalinovich, Olesya Kazakova, Katja Vlasov, Maxim Ponomarenko, Martin Winter
Department of Life Sciences and Chemistry, Jacobs University Bremen, Campus Ring 1, D-28759 Bremen, Germany

12:10
B2.7
Salts of perhalogenoalkylhalogenoborate anions
L. A. Bischoff, J. A. P. Sprenger, C. Kerpen, N. V. Ignat’ev and M. Finze
Julius-Maximilians-Universität Würzburg, Germany


12:30 - 14:00
Lunch

Chair: K.Koppe
14:00
B2.8-IL
Nanostructured AlF3-based materials: versatile solvothermal preparation
T. Skapin
Jožef Stefan Institute, Ljubljana, Slovenia

14:30
B2.9-IL
Haloperfluorocarbons-anions recognition and self-assembly: structural and functional aspects
G. Resnati, G. Cavallo, V. Kumar, P. Metrangolo, G. Terraneo
NFMLab-Dept. Chemistry, Materials, and Chemical Engineering “Giulio Natta”, Politecnico di Milano;via Mancinelli 7; 20131 Milano, Italy

15:00
B2.10
Nitramines in Superacids. Where Does the Proton Go?
Thomas Saal, Martin Rahm, Ralf Haiges, Karl O. Christe
Department of Chemistry and Loker Hydrocarbon Research Institute, University of Southern California, 837 Bloom Walk, Los Angeles, California 90089-1661, USA

15:20 - 15:50
Coffee break

Chair: D. O’HAGAN
15:50
B2.12-IL
Fluorinated alkenes and acetylenes in the synthesis of practically useful compounds
Nenajdenko V. G.
Moscow State University, Department of Chemistry, Leninskie Gory, Moscow 119992, Russia

16:20
B2.13
The Pentafluoroethylstannates [SnIV(C2F5)5]- and [SnII(C2F5)3]-
M. Wiesemann and B. Hoge
Bielefeld University, Center for Molecular Materials Universitaetsstr. 25, 33615 Bielefeld, Germany

16:40
B2.11
Surface chemistry of silicon texturized with HF
Robert P. Socha, Aneta Kędra, Małgorzata Zimowska, Piotr Panek, Marek Lipiński, Piotr Warszyński
Jerzy Haber Institute of Catalysis and Surface Chemistry PAS, Kraków, Poland

17:00 - 20:00
Poster Session with food & drinks

THURSDAY, AUGUST

11

STREAM A
Chair: T. Brigaud
9:00
A3.1-IL
Stereocontrolled Synthesis of Fluorinated Aminophosphonates
K. Margas-Musielak, P. Mrowiec, M. Rapp, M. Szewczyk, T. Cytlak, M. Kaźmierczak, H.Koroniak
JFaculty of Chemistry, Adam Mickiewicz University, Poznań, Poland

9:30
A3.2-IL
Photoredox catalysis: a great opportunity for the generation of the trifluoromethyl radical. Extension to multicomponent reactions.
Emmanuel Magnier
Institut Lavoisier de Versailles UMR 8180, Universitй de Versailles-St-Quentin, 45 Av. des Etats-Unis, 78035 Versailles cedex, France

10:00
A3.3
Trifluoromethylated thiopyranoid glycal analogs: synthesis and reactions with nucleophiles
Serhii Siryi, Vadim Timoshenko, Yurii Shermolovich
Institute of Organic Chemistry, NAS of Ukraine

10:20
A3.4
Difluorinated Silyl Enol Ethers As Novel Substrates In The Saegusa-Ito Cyclisation – A New Strategy For Accessing Selectively Fluorinated Cyclohexenones
Adam McCarter, Jonathan. M. Percy, David Hirst
WestCHEM Department of Pure and Applied Chemistry, University of Strathclyde, UK

10:40 - 11:10
Coffee break

Chair: B. Langlois
11:10
A3.5-IL
Elemental Fluorine a most versatile reagent
Shlomo Rozen
School of Chemistry, Tel Aviv University, Israel, 69978

11:40
A3.6
Arene Chromium Tricarbonyl Complexes – a Novel Approach to Unknown Perfluoroalkyl Cyclohexadienes
Glib Yu. Khrapach, Nataliia V. Kirij, Yurii L. Yagupolskii
Institute of Organic Chemistry of NAS of Ukraine, Kyiv, Ukraine

12:00
A3.7
Corannulenes with strong electron-withdrawing groups
A. Haupt, D. Lentz
Freie Universität Berlin, Germany

12:20

12:40 - 14:00
Lunch

Chair: J.-F. Paquin
14:00
A3.8-IL
Trifluoromethyl Thiopyranes as precursor of Fluorine containing Thiosugars analogs
Vadim Timoshenko, Sergiy Siry, Yuriy Shermolovich
Institute of organic chemistry, NAS of Ukraine, Murmanska, 5, Kyiv, 02094,Ukraine

14:30
A3.9
Direct Electrophilic (Benzenesulfonyl)Difluoromethylthiolation with a New Shelf-Stable Reagent
Ermal Ismalaj, Didier Le Bars, Thierry Billard
Institute of Chemistry and Biochemistry, CNRS & University of Lyon 1, Lyon, France CERMEP, Imagerie du Vivant, PET Department, Lyon, France

14:50
A3.10
Direct electrophilic trifluoromethylselenolation of nucleophiles
Q. Glenadel , T. Billard
Institute of Chemistry and Biochemistry, CNRS & University of Lyon, Lyon, France

15:10 - 15:40
Coffee break

Chair: B. Hoge
15:40
A3.11

16:00
A3.12
Enzymatic resolution of fluorinated heterylalkanols and cycloalkanols
A.O. Kolodiazhnaya, O.V. Kucher, O.O. Kolodiazhnaya, D.V. Prisuazhnyk, A.A. Tolmachev
Institute of Bioorganic Chemistry and Petrochemistry, Ukraine Enamine Ltd., Ukraine

16:20
A3.13
Amides of polyfluoroalkanethiocarboxylic acids in the synthesis of fluorinated compounds
Sergiy S. Mykhaylychenko, Nadiia V. Pikun, Yuriy G. Shermolovich
Institute of Organic Chemistry NAS of Ukraine, Murmanska, 5, Kyiv, 02094,Ukraine

STREAM B
Chair: S. Hasenstab-Riedel
9:00
B3.1-IL
Visible light-induced reaction of difluoromethylated phosphonium salts as difluoromethyl radical source
Feng-Ling Qing
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China

9:30
B3.2-IL
Functionalized alkyl(perfluoroalkyl)phosphinic acids: Synthesis, properties and applications
Karsten Koppe, Vural Bilir, Walter Frank, Nikolai Ignat’ev
Performance Materials – Fluorine Chemistry R&D, Merck KGaA, Darmstadt, Germany

10:00
B3.3
Fluorinated and cyclic organophosphorus compounds synthesis in superacid
U. Castelli, A. Mingot, J. F. Lohier, C. Witulski-Alayrac, A.C. Gaumont, S. Thibaudeau
Institut de Chimie des Milieux et des Matйriaux de Poitiers - Universitй de Poitiers - France

10:20
B3.4
The introduction of P-F bonds using aqueous fluoride ion and a water soluble carbodiimide: a convenient alternative synthesis of phosphorofluoridates, phosphonofluoridates and phosphinofluoridates.
Michael F. Aldersley, Prakash C. Joshi, Scott A. McCallum and Anthony J. Kirby
Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, NY 12180, USA

10:40 - 11:10
Coffee break

Chair: M. Finze
11:10
B3.5-IL
Fluorinated arylcyclopropylamines: synthesis, physical-chemical properties and inhibitor potencies against Monoamine Oxidases.
Günter Haufe
Organic Chemistry Institute and Cells-in-Motion Center of Excellence, University of Münster, Germany

11:40
B3.6
Effects of fluoride on the expression of steroidogenesis genes in TM3 Leydig cells
B. Orta-Yılmaz, M. Erkan
İstanbul Universty, Turkey

12:00
B3.7
N-arylsulfamoylbenzenesulfonyl fluorides as inhibitors of serine proteases
Petro Borysko, Maria Kliachyna, Sergey Zozulya, Oleksandr Vasylchenko, Andrey Bogolubsky, Yurii Moroz, Pavel Mykhailiuk, and Andrey Tolmachev
Enamine Ltd., 78 Chervonotkatska Street, Kyiv, 02094, Ukraine

12:20
B3.8
Electrochemical synthesis of carbon fluorooxide nanoparticles from silicon carbide
Sergei Alekseev, Dmytro Korytko, Bohdan Oliinyk and Vladimir Lysenko
Faculty of Chemistry, Taras Shevchenko National University of Kyiv, 64 Volodymyrska Street, Kyiv-01601, Ukraine

12:40 - 14:00
Lunch

Chair: T.Braun
14:00
B3.9-IL
Validation and application of trifluoromethyl-containing conformationally restricted amino acids as 19F-NMR labels to study membrane-active peptides
Sergii Afonin, Oleg Babii, Marina Berditsch, Olivier Cheneval, David J. Craik, Stephan L. Grage, Sуnia Henriques, Oleg M. Michurin, Pavel Mykhailiuk, Dmytro S. Radchenko, Anton A. Tkachenko, Anne S. Ulrich, Igor V. Komarov
Taras Shevchenko National University of Kyiv, Kyiv, Ukraine Enamine Ltd., Kyiv, Ukraine

14:30
B3.10
19F NMR labels with charged side chains: trifluoromethyl-containing conformationally restricted analogues of lysine, arginine, and glutamic/aspartic acid
D.S. Radchenko, O.M. Michurin, S. Afonin, M. Berditsch, A.S. Ulrich, I.V. Komarov
Institute of High Technologies, Ukraine; Enamine Ltd., Ukraine

14:50
B3.11
Chiral recognition properties of optically active α-(nonafluoro-tert-butoxy)carboxylic acids
Anikó Nemes, Tamás Csóka, Szabolcs Béni, Viktor Farkas, József Rábai, Dénes Szabó
Eötvös Loránd University, Budapest, Hungary

15:10 - 15:40
Coffee break

Chair: G. Resnati
15:40
B3.12
Mixed tantalum and niobium fluoroanions
Gašper Tavčar, Evgeny Goreshnik
Jožef Stefan Institute, Ljubljana Slovenia

16:00
B3.13
FeO-induced efficient decomposition of fluorinated room-temperature ionic liquid to fluoride ions in subcritical and supercritical water
Hisao Hori, Akihiro Takahashi, Takaaki Ito
Department of Chemistry, Faculty of Science, Kanagawa University, 2946 Tsuchiya, Hiratsuka 259-1293, Japan

16:20
B3.14
Photodecomposition of perfluorooctanoic acid catalyzed by TiO2: the effect of oxygen in the photocatalytic oxidation pathways
Maurizio Sansotera, Federico Persico, Alberto Baggioli, Walter Navarrini
Dipartimento di Chimica, Materiali e Ingegneria Chimica ‘‘Giulio Natta’’, Politecnico di Milano, Milano, Italy Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM), Firenze, Italy

FRIDAY, AUGUST

12

STREAM A
Chair: H. Koroniak (to be confirmed)
9:30
A4.1
Cu-catalyzed (multi)borylation of (multi)fluoroarenes via C–F bond cleavage
Takashi Niwa, Hidenori Ochiai, Takamitsu Hosoya
Division of Bio-Function Dynamics Imaging, RIKEN Center for Life Science Technologies

9:50
A4.2
An efficient and greener approach for synthesis of fluorinated organic compounds
Surender Kumar Dhingra, Purnima Nag, Rahul Saxena
Research and Development Centre, SRF Limited, Bhiwadi, Rajasthan-301019, India

10:30 - 11:00
Coffee break

11:00
Closing Remarks

STREAM B
Chair: G. Mlostoń
9:30
B4.1
On the Reactivity of Fluorinated α-Methylstyrenes in Radical Copolymerizations with Various Alkenes
J. Walkowiak-Kulikowska, A. Szwajca, J. Wolska, H. Koroniak, V. Gouverneur, B. Ameduri
Adam Mickiewicz University, Poznań, Poland

9:50
B4.2
Perfluorinated polymers in membrane gas separation
N.A. Belov, Yu.P. Yampolskii
A.V. Topchiev Institute of Petrochemical Synthesis of RAS

10:10
B4.3
Plasma deposition of a fluoropolymer nanocoating onto carbon fibers for improving their compatibility with PTFE matrix
S. F. Zhandarov, V. A. Shelestova, E. M. Tolstopyatov, P. N. Grakovich, and L. F. Ivanov
“V. A. Bely” Metal-Polymer Research Institute of the National Academy of Sciences of Belarus

10:30 - 11:00
Coffee break

11:00
Closing Remarks


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